Calculate the fequency of light emitted (for the first 3, and absorbed for the second 3) when each of the following energy transitions occurs in the hydrogen atom:
a) n=3 to n=2
b) n=4 to n=1
c) n=2 to n=1
a) n=3 to n=4
b) n=3 to n=6
c) n=3 to n=5
Even if you don't work them out just please tell me how to figure this out!!!
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Verified answer
Use the Rydberg formula, which gives you the wave length for the jump from level n2 to level n1:
1/λ = RH · ( 1/(n1)² - 1/(n2)² )
RH = 1.0967758×10^7m^-1 is the Rydberg constant for hydrogen
Wavelength and frequency are related by:
ν = c/λ
c = 2.99792458×10^8m/s
Combine both equations to:
ν = ν₀ · ( 1/(n1)² - 1/(n2)² )
with ν₀ = c · RH = 3.28805×10^15Hz
For the first set of problems i get the following results.
a) ν = 0.4567×10^15Hz
b) ν = 3.0825×10^15Hz
c) ν = 2.4660×10^15Hz
In the second set of problems light is absorbed to raise the electron to a higher level. Because the energy difference of the is the same as for a jump in the reverse direction, the frequency of the light absorbed is the same as of the light emitted by reverse jump. Hence you can use the formula above.
a) ν = 0.1598×10^15Hz
b) ν = 0.2740×10^15Hz
c) ν = 0.2338×10^15Hz