How Do You IV Train Pok'emon?

I played Pok'emon since the beginning and ususally up my team of 6 and a couple of reserves to 100. I never understood how to up stats up with IV training. I on occasion will boost its weakest stat with a vitamin but that is it. I am about to start Pok'emon White and want to know how to make my Po'meon strong through this IV method I have read about on the net. At times I am not happy with a HP total or a stat and vitamins seem to be disabled after about level 60. Is it heavy vitamins, certain natures, and grueling training or what?

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