How do you write lead guitar parts?

I am pretty far off in the music world and I understand mostly everything in basic music theory. But my question was how to write lead guitar parts. I like post-hardcore bands like Memphis May Fire and Hands Like Houses just to give an idea of my music style. I've heard of the 12 bar blues and know that you solo in the A minor pentatonic scale with it. when in comes down to in how do they get A minor pentatonic? Why not E minor pentatonic or D minor pentatonic (the other chords the 12 bar blues consists of). If I play a G-C-D-Em what scale would I solo over or is a certain key. If it is a key then what is the fastest way to find the key your in when writing music for a band?

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