Ideal gas law problems?

a.)When heated, calcium carbonate decomposes to yield calcium oxide and carbon dioxide gas via the reaction

CaCO3(s)→CaO(s)+CO2(g)

How many grams of calcium carbonate are needed to produce 39.0L of carbon dioxide at STP?

b.)Butane, C4H10, is a component of natural gas that is used as fuel for cigarette lighters. The balanced equation of the complete combustion of butane is

2C4H10(g)+13O2(g)→8CO2(g)+10H2O(l)

At 1.00 atm and 23 ∘C, how many liters of carbon dioxide are formed by the combustion of 3.20g of butane?

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