How must I use Nero to copy data from my PC onto an empty external CD?

I tried it with another CD first. After the burning process was complete, I inserted the disk again into the drive to see if it had worked. When I double-clicked on the CD-drive icon, it asked me to insert a disk! It treated the CD as if it were never there. HELP ME! I need it badly for my project. Also, if using Nero is not the right way, what is?

The CD-drive also shows '52X max'. Is that supposed to be the maximum speed of the drive? Or is it the only speed the drive runs on? My CD is 1X - 48X compatible.

Update:

Nero's bar limit is way beyond 800 MB. The maximum my CD can take is 700 MB

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